Infrared and Raman spectra, conformational stability, vibrational assignment and ab initio calculations of methylvinyl silyl chloride

JR Durig, SW Hur, GA Guirgis

Index: Durig, James R.; Hur, Seung Won; Guirgis, Gamil A. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2003 , vol. 59, # 11 p. 2449 - 2471

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Citation Number: 4

Abstract

The infrared spectra (3200–50 cm− 1) of gaseous and solid and Raman spectra (3200–10 cm− 1) of the liquid and solid methylvinyl silyl chloride, CH2 CHSiH (CH3) Cl, and the Si-d isotopomer have been recorded. The three expected stable conformers (the three different groups eclipsing the double bond) have been identified in the fluid phase, but it was not possible to obtain an annealed solid with a single conformer. Variable temperature (− 105 ...