Reaction of substituted lithium amides with diborane

LD Schwartz, PC Keller

Index: Schwartz,L.D.; Keller,P.C. Journal of the American Chemical Society, 1972 , vol. 94, p. 3015 - 3018

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Citation Number: 25

Abstract

Abstract: The stepwise addition of diborane to diethyl ether solutions of N-alkyl-substituted lithium amides (LiNHR, R= CH3, CzHs, n-C3H7, iC, H?, n-C4Hg, sec-CaH9, tertGH9, and n- C5H11; LiNR2', R'= CH3, C2H5, n-C3H7, and i-C3H7) at room temperature has been studied. The course of the reactions has been monitored by boron-1 1 nmr; in almost all cases species so detected have been isolated and identified. When the amide is still in ...

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