Organic letters

Low-temperature deacylation of N-monosubstituted amides

A Spaggiari, LC Blaszczak, F Prati

Index: Spaggiari, Alberto; Blaszczak, Larry C.; Prati, Fabio Organic Letters, 2004 , vol. 6, # 22 p. 3885 - 3888

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Citation Number: 27

Abstract

The (PhO) 3P⊙ Cl2 reagent, prepared in situ by titrating a solution of triphenyl phosphite with chlorine, is used to convert N-monosubstituted amides into their corresponding amines. The reaction, if compared to other traditional methods, shows the advantage of very mild conditions and low temperature (-30° C→ rt).

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