Synthesis and mass spectrometric study of α, ω-diallylpermethyloligosilanes

…, NA Chernyavskaya, AI Chernyavskii

Index: Larkin; Pleshkova; Kononova; Chernyavskaya; Chernyavskii Russian Chemical Bulletin, 2004 , vol. 53, # 10 p. 2224 - 2228

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Abstract

Abstract Representatives of the homologous series of α, ω-diallylpermethyloligosilanes were synthesized for the first time by the reaction of α, ω-dichloropermethyloligosilanes Cl (Me 2 Si) n Cl (n= 2–6) with allylmagnesium chloride. Fragmentation of α, ω- diallylpermethyloligosilanes under electron impact ionization was studied by mass spectrometry.