Organometallic compounds of group III: XIVV. Orientation in the hydralumination of conjugated olefin hydrocarbons. Behavior of allylic organoaluminum systems

JJ Eisch, GR Husk

Index: Eisch,J.J.; Husk,G.R. Journal of Organometallic Chemistry, 1974 , vol. 64, p. 41 - 55

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Citation Number: 15

Abstract

Abstract In order to evaluate steric and electronic factors in the hydralumination of p π-and d π-conjugated olefins, the following compounds have been treated with diisobutylaluminum hydride: 1, 1-diphenylethylene; 1, 1-diphenylallene; 1, 1-diphenyl-1, 3-butadiene; acenaphthylene; triethylvinylsilane; and triphenylvinylsilane. The sites of the resulting carbon—aluminum bonds in the adducts have been deduced by a combination of NMR ...