Mechanistic aspects of gas-phase photodecarbonylation reactions of bicyclo [3.1. 0] hexanones

PS Mariano, E Bay, DG Watson, T Rose…

Index: Mariano, Patrick S.; Bay, Elliott; Watson, Darrell G.; Rose, Timothy; Bracken, Christopher Journal of Organic Chemistry, 1980 , vol. 45, # 10 p. 1753 - 1762

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Citation Number: 11

Abstract

The gas-phase photodecarbonylation and photofragmentation reactions of substituted bicyclo [3.1. 0] hexan-3-ones have been studied in detail. Photolysis of these ketones yields 1, 3-dienes, vinylcyclopropanes, and 1, l-dienes as detectable products. The possible mechanisms for these reactions are discussed in light of the regiochemical and stereochemical results obtained. In addition, methyl substitution at C-6 and C-2 of these ...

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