Product Study of the OH Radical and Cl Atom Initiated Oxidation of 1, 3??Dioxane
J Moriarty, JC Wenger, HW Sidebottom
Index: Moriarty, Jennie; Wenger, John C.; Sidebottom, Howard W. ChemPhysChem, 2010 , vol. 11, # 18 p. 3980 - 3986
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Abstract
Abstract The products of the hydroxyl (OH) radical and chlorine (Cl) atom initiated oxidation of 1, 3-dioxane are determined under various reaction conditions in a 50 L teflon reaction chamber using FTIR spectroscopy for analysis. The major products detected in all experiments are (2-oxoethoxy) methyl formate, formic acid and methylene glycol diformate with average molar yields of 0.50±0.05, 0.41±0.02 and 0.03±0.01 respectively for the OH ...
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