Palladium-catalyzed, direct boronic acid synthesis from aryl chlorides: a simplified route to diverse boronate ester derivatives

GA Molander, SLJ Trice, SD Dreher

Index: Molander, Gary A.; Trice, Sarah L. J.; Dreher, Spencer D. Journal of the American Chemical Society, 2010 , vol. 132, # 50 p. 17701 - 17703

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Citation Number: 143

Abstract

Although much current research focuses on developing new boron reagents and identifying robust catalytic systems for the cross-coupling of these reagents, the fundamental preparations of the nucleophilic partners (ie, boronic acids and derivatives) has been studied to a lesser extent. Most current methods to access boronic acids are indirect and require harsh conditions or expensive reagents. A simple and efficient palladium- ...

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