The Journal of Organic Chemistry

Reactions of alkyl acrylates and acrylonitrile with guanidine in dimethylformamide

K Sugino, T Tanaka

Index: Sugino,K.; Tanaka,T. Journal of Organic Chemistry, 1968 , vol. 33, # 8 p. 3354 - 3355

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Citation Number: 8

Abstract

The reaction of acrylic esters or acrylonitrile with guanidine has not previously been reported. We have found that, on addition of different alkyl acrylates to a DMF solution of free guanidine, a basic compound (1') separated in almost quantitative yield. No C= C double bond was detected by infrared analysis or by the reaction of potassium permanganate or bromine with 1'. Hydrolysiis of the compound with water gave the guanidinium salt 11', ...

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