Applied Organometallic Chemistry

Double Suzuki cross??coupling reaction of pyrimidine boronic acid: synthesis of new versatile dielectrophile

MM Naseer, S Hameed

Index: Naseer, Muhammad Moazzam; Hameed, Shahid Applied Organometallic Chemistry, 2012 , vol. 26, # 7 p. 330 - 334

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Citation Number: 3

Abstract

The double Suzuki cross-coupling reaction has successfully been applied for the synthesis of 5, 5′-(5-butoxy-1, 3-phenylene) bis (2-chloropyrimidine) with two reactive chloro groups and an alkoxy side chain starting from 2-chloropyrimidin-5-ylboronic acid and 1, 3-dibromo- 5-butoxybenzene. The reactivity of this dielectrophile was tested by reaction with aniline and phenol, a nitrogen and oxygen nucleophile, respectively. The new dielectrophile would ...