Tetrahedron

Addition, substitution, and telomerization reactions of olefins in the presence of metal carbonyls or colloidal iron

AN Nesmeyanov, RK Freidlina, EC Chukovskaya…

Index: Nesmeyanov,A.N. et al. Tetrahedron, 1962 , vol. 17, p. 61 - 68

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Citation Number: 85

Abstract

THERE are about fifty reactions known to be catalysed by metal carbonyls, 1 those for olefins being mainly of three types such as carbonylation, hydrogenation and isomerization. They are essentially effected in the presence of carbon monoxide and metal carbonyls under 400 atm and up to 300. Reactions that seem to be similar to those catalysed by metal carbonyls also proceed on the surface of the catalysing metal in the presence of carbon ...

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