Intramolecular Cascade Hydroarylation/Cycloisomerization Strategy for the Synthesis of Polycyclic Aromatic and Heteroaromatic Systems

…, M Bernard, J Sýkora, J Karban…

Index: Storch, Jan; Bernard, Martin; Sykora, Jan; Karban, Jindrich; Cermak, Jan European Journal of Organic Chemistry, 2013 , # 2 p. 260 - 263

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Citation Number: 11

Abstract

Abstract A new PtCl 2/PtCl 4-catalyzed hydroarylation/cycloisomerization cascade reaction leading to the formation of two aromatic or heteroaromatic rings in one step is reported. The strategy developed is exemplified by the synthesis of the 5, 6-dihydrobenzo [c] phenanthrene and 6H-naphtho [2, 1-c] chromene skeletons. Attempts to prepare [8] helicene- like molecules are also discussed.

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