The condensation of 2-nitroethanol with the d-aldopentoses

JC Sowden, DR Strobach

Index: Sowden; Strobach Journal of the American Chemical Society, 1958 , vol. 80, p. 2532

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Citation Number: 19

Abstract

A preliminary communication'from this Laboratory reported the condensation of sodium aci-2- nitroethanol with D-arabinose to give, after hydrolysis of the intermediate sodium aci-2- deoxy-2-nitroheptitols, D-gluco-heptulose and D-mannoheptulose. The synthesis now has been extended to D-lyxose, D-xylOSe and D-ribose to give, respectively, D-galacto- heptulose plus D-tdo-heptulose, 2 7-anhydro-PD-ido-heptulopyranose and 2, 7-anhy-dro- ...