Synthesis of allyl and alkyl vinyl ethers using an in situ prepared air-stable palladium catalyst. Efficient transfer vinylation of primary, secondary, and tertiary alcohols
M Bosch, M Schlaf
Index: Bosch, Martin; Schlaf, Marcel Journal of Organic Chemistry, 2003 , vol. 68, # 13 p. 5225 - 5227
Full Text: HTML
Citation Number: 70
Abstract
An air-stable palladium catalyst formed in situ from commercially available components efficiently catalyzed the transfer vinylation between butyl vinyl ether and various allyl and alkyl alcohols to give the corresponding allyl and alkyl vinyl ethers in 61-98% yield in a single step.
Related Articles:
[Kupczyk-Subotkowska, Lidia; Saunders Jr., William H.; Shine, Henry J.; Subotkowski, Witold Journal of the American Chemical Society, 1993 , vol. 115, # 14 p. 5957 - 5961]
[Price,C.C.; Balsley,R.B. Journal of Organic Chemistry, 1966 , vol. 31, p. 3406 - 3407]
[Gajewski,J.J.; Jurayj,J.; Kimbrough,D.R. Journal of the American Chemical Society, 1987 , vol. 109, p. 1170]
[Crandall,J.K.; Mayer,C.F. Journal of Organic Chemistry, 1970 , vol. 35, # 9 p. 3049 - 3053]
[Paul et al. Bulletin de la Societe Chimique de France, 1950 , p. 121,126]