Chemical activation study of the reactions of methylene with oxetan and 3, 3-dimethyloxetan
HM Frey, IM Pidgeon
Index: Frey, Henry M.; Pidgeon, Ivy M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1983 , vol. 79, p. 1237 - 1248
Full Text: HTML
Citation Number: 0
Abstract
Methylene (singlet) formed by the photolysis of ketene (313 nm) reacts with oxetan to yield 2- methyl-and 3-methyloxetans by insertion in the C—H bonds and probably also tetrahydrofuran. These products are formed chemically activated and undergo unimolecular decomposition unless collisionally stabilized. Using perfluoropropane as the bath gas, the results obtained with 2-methyloxetan have been interpreted using RRKM theory and a ...
Related Articles:
[Pihlaja, Kalevi; Aaljoki, Kari; Lyytinen, Maija-Riitta; Huusko, Marja-Liisa; Hotokka, Marjut Arkivoc, 2011 , vol. 2011, # 5 p. 188 - 199]
[Friedrich, Klaus; Jansen, Ulrich; Kirmse, Wolfgang Tetrahedron Letters, 1985 , vol. 26, # 2 p. 193 - 196]
[Friedrich, Klaus; Jansen, Ulrich; Kirmse, Wolfgang Tetrahedron Letters, 1985 , vol. 26, # 2 p. 193 - 196]
[Yamamoto, Shunzo; Takahoso, Hiroshi; Sueishi, Yoshimi; Nishimura, Norio Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 7 p. 2038 - 2042]
[Yamamoto, Shunzo; Takahoso, Hiroshi; Sueishi, Yoshimi; Nishimura, Norio Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 7 p. 2038 - 2042]