Preferential Replacement Reactions of Highly Fluorinated Alkyl Halides. II. 1 Some Reactions of Fluorinated Allyl Iodides2, 3

AH Fainberg, WT Miller Jr

Index: Fainberg; Miller Journal of the American Chemical Society, 1957 , vol. 79, p. 4170,4174

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Citation Number: 34

Abstract

'111e preferciitiul rcplaceiimit uf iotliiie in 3-iodoperitafluoropropeiie and i~ i%-clilort~.: i- iodot~~ ra~ luoru~ i apeiie by reactiiJl1 with chlorine and bromiue and with chloride and bromide ions is described. Ionic aiid free radical type reaction mechaiiisnlr wliich involve initial reagent attack at the double bond rather thnn at the allylic carbon atom are proposed for these reactions. The reactions with lialidc ioil are shown to be reversible. Treatment of ...