Allosteric Effects in Binuclear Homo-and Heterometallic Triple-Stranded Lanthanide Podates

…, G Canard, S Koeller, B Bocquet, C Piguet

Index: Ryan, Patrick E.; Canard, Gabriel; Koeller, Sylvain; Bocquet, Bernard; Piguet, Claude Inorganic Chemistry, 2012 , vol. 51, # 18 p. 10012 - 10024

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Abstract

*E-mail: Gabriel.Canard@univ-amu.fr (GC), Claude.Piguet@unige.ch (CP). ... Tunable interstrand interactions combined with size-dependent effective molarities are exploited for the selective complexation of different lanthanide cations in binuclear podates. ... This work illustrates a simple approach for deciphering and exploiting the various free energy contributions to the global complexation process leading to the binuclear triple-stranded podates [Ln 2 (L9)] 6+ (Ln is a trivalent ...

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