Highly Branched Alkylphosphorus Compounds. II. Synthesis of 1, 1, 2-Trimethylpropylphosphonyl Chloride1

SH Metzger, OH Basedow, AF Isbell

Index: Metzger,S.H. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 627 - 630

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Citation Number: 13

Abstract

The reaction of 2-chloro-2, 3dimethylbutane with phosphorus trichloride and aluminum chloride does not give the expected product, but instead produces t-butylphosphonyl chloride as the predominant product. The reaction of Grignard reagents with N, N- diethylphosphoramidic dichloride was extended to include t-alkyl Grignard reagents. 1, 1, 2- Trimethylpropylphosphonyl chloride could not be prepared by the normal procedures, ...