The synthesis of N-heterocycles using ortho-metallated primary benzylamine complexes of palladium (II) and platinum (II)

RD O'Sullivan, AW Parkins

Index: O'Sullivan, Richard D.; Parkins, Adrian W. Journal of the Chemical Society, Chemical Communications, 1984 , # 17 p. 1165 - 1166

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Citation Number: 36

Abstract

The synthesis of the isoindolinimines (5) by the insertion of isocyanides into the metal– carbon bond of the ortho-palladated primary benzylamine complex (1a) is described; the novel oxidative addition and susbsequent reductive elimination of the ortho-metallated primary benzylamine–platinum complex (6) yields 3-oxo-1, 2, 3, 4-tetrahydroisoquinoline (8).

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