Ru (III)-catalyzed oxidative reaction in ionic liquid: an efficient and practical route to 2-substituted benzothiazoles and their hybrids with pyrimidine nucleoside
X Fan, Y Wang, Y He, X Zhang, J Wang
Index: Fan, Xuesen; Wang, Yangyang; He, Yan; Zhang, Xinying; Wang, Jianji Tetrahedron Letters, 2010 , vol. 51, # 27 p. 3493 - 3496
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Citation Number: 21
Abstract
An efficient, practical and environmentally benign synthesis of 2-substituted benzothiazoles was developed through RuCl3-catalyzed oxidative condensation of 2-aminothiophenol with aldehyde in ionic liquid by using air as the oxidant. With this procedure, a series of 2- substituted benzothiazoles and benzothiazole/pyrimidine nucleoside hybrids with antimicrobial activities were efficiently prepared from easily accessible starting materials.
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