Organometallics

Synthesis, characterization, and reactivity of triphenylsilyl, triphenylgermyl, and triphenylstannyl derivatives of zirconium and hafnium

HG Woo, WP Freeman, TD Tilley

Index: Woo, Hee-Gweon; Freeman, William P.; Tilley, T. Don Organometallics, 1992 , vol. 11, p. 2198 - 2205

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Citation Number: 59

Abstract

2, 6-Me2C6H3NC to give $-iminosilaacyl insertion products, 88 does the germyl 3. However, no reaction is observed between 2, 6-Me2C6H NC and stannyl complexes 7 or 10. These investigations establish the reactivity trends M-SiPh,> M-dePh,> M-SnPh, for u-bond metathesis processes with hydrogen and phenylsilane and for insertion reactions with carbon monoxide and 2, 6-Me2C6H3NC. It is suggested that, for these analogues do ...