Reaction Mechanism for the LiCl??Mediated Directed Zinc Insertion: A Computational and Experimental Study

…, A Muranaka, K Morokuma, M Uchiyama

Index: Liu, Ching-Yuan; Wang, Xuan; Furuyama, Taniyuki; Yasuike, Shuji; Muranaka, Atsuya; Morokuma, Keiji; Uchiyama, Masanobu Chemistry - A European Journal, 2010 , vol. 16, # 6 p. 1780 - 1784

Full Text: HTML

Citation Number: 1

Abstract

In situ generation of organozinc reagents and their integration into CÀC bond-forming processes are of continuing interest because of the characteristically high chemo-and stereoselectivity.[1] In 2006, Knochel and co-workers discovered that the oxidative insertion of zinc dust into aryl halides is drastically accelerated in the presence of LiCl, thereby opening up a practical and efficient preparation method for aryl-and alkylzinc reagents.[2] ...

Related Articles:

Halodeboronation of organotrifluoroborates using tetrabutylammonium tribromide or cesium triiodide

[Yao, Min-Liang; Kabalka, George W.; Blevins, David W.; Reddy, Marepally Srinivasa; Yong, Li Tetrahedron, 2012 , vol. 68, # 19 p. 3738 - 3743]

Copper-catalyzed halogenation of arylboronic acids

[Zhang, Guangyou; Lv, Guanglei; Li, Liping; Chen, Fan; Cheng, Jiang Tetrahedron Letters, 2011 , vol. 52, # 16 p. 1993 - 1995]

Halogen Exchange via a Halogenation of Diaryliodonium Salts with Cuprous Halide

[Li, Jian; Liu, Li; Ding, Dong; Sun, Jiang-Tao Letters in Organic Chemistry, 2013 , vol. 10, # 8 p. 541 - 548]

Palladium-Catalyzed Cleavage Reaction of Carbon− Carbon Triple Bond with Molecular Oxygen Promoted by Lewis Acid

[Wang, Azhong; Jiang, Huanfeng Journal of the American Chemical Society, 2008 , vol. 130, # 15 p. 5030 - 5031]

Copper-catalyzed methyl esterification of aromatic aldehydes and benzoic alcohols by TBHP as both oxidant and methyl source

[Li, Pan; Zhao, Jingjing; Lang, Rui; Xia, Chungu; Li, Fuwei Tetrahedron Letters, 2014 , vol. 55, # 2 p. 390 - 393]

More Articles...