A Novel Synthesis of Indandiones Using the HOF⊙ CH3CN Complex

S Dayan, J Almog, O Khodzhaev…

Index: Dayan, Sharon; Almog, Joseph; Khodzhaev, Oleg; Rozen, Shlomo Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2752 - 2754

Full Text: HTML

Citation Number: 19

Abstract

During the past few years, the HOF ‚CH3CN complex has proven to be one of the best oxygen-transfer agents organic chemistry has to offer. This feature arises from the nature of the OF bond where the oxygen is bonded to the most electronegative fluorine, turning it into a very strong electrophile indeed. The complex is easily prepared by bubbling either a commercial or a self-prepared mixture of 10-15% F2 in nitrogen through aqueous ...

Related Articles:

Investigations of the reaction mechanisms of 1, 2-indanediones with amino acids

[Petrovskaia; Taylor; Hauze; Carroll; Joullie Journal of Organic Chemistry, 2001 , vol. 66, # 23 p. 7666 - 7675]

Selective Alkene Oxidation with H2O2 and a Heterogenized Mn Catalyst: Epoxidation and a New Entry to Vicinal cis??Diols

[De Vos, Dirk E.; De Wildeman, Stefaan; Sels, Bert F.; Grobet, Piet J.; Jacobs, Pierre A. Angewandte Chemie - International Edition, 1999 , vol. 38, # 7 p. 980 - 983]

Emulation of racemase activity by employing a pair of stereocomplementary biocatalysts

[Gruber, Christian C.; Nestl, Bettina M.; Gross, Johannes; Hildebrandt, Petra; Bornscheuer, Uwe T.; Faber, Kurt; Kroutil, Wolfgang Chemistry - A European Journal, 2007 , vol. 13, # 29 p. 8271 - 8276]

A novel method for protection and deprotection of the carbonyl groups in 1, 2-indanedione by conversion to dioxa-dithiapropellanes

[Almog, Joseph; Zehavy, Yirmi; Cohen, Shmuel Tetrahedron Letters, 2003 , vol. 44, # 16 p. 3285 - 3288]

A novel method for protection and deprotection of the carbonyl groups in 1, 2-indanedione by conversion to dioxa-dithiapropellanes

[Almog, Joseph; Zehavy, Yirmi; Cohen, Shmuel Tetrahedron Letters, 2003 , vol. 44, # 16 p. 3285 - 3288]

More Articles...