Novel synthesis of phenol derivatives by palladium-catalysed cyclocarbonylation of penta-2, 4-dienyl acetates

Y Ishii, C Gao, M Iwasaki, M Hidai

Index: Ishii, Youichi; Gao, Chao; Iwasaki, Masakazu; Hidai, Masanobu Journal of the Chemical Society, Chemical Communications, 1991 , # 10 p. 695 - 696

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Citation Number: 4

Abstract

Palladium-catalysed cyclocarbonylation of penta-2,4-dienyl acetates in the presence of NEt, and Ac20 selectively gives phenyl acetates in good yields. ... Catalytic cyclocarbonylation has been attracting much atten- tion in recent years because of its potentiality as a synthetic tool. 1-3. We have recently developed palladium-catalysed cyclocarbonylation of 3-arylallyl acetates and bromides such as cinnamyl acetate to give fused aromatic compounds via acylation ...

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