A Novel CC Single-Bond Formation Accompanying CO Bond Cleavage by Use of a Ketone, an Alkylating Reagent, and a Low-Valent Vanadium Complex in …

Y Kataoka, H Akiyama, I Makihira…

Index: Kataoka, Yasutaka; Akiyama, Hiroaki; Makihira, Isamu; Tani, Kazuhide Journal of Organic Chemistry, 1997 , vol. 62, # 23 p. 8109 - 8113

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Citation Number: 7

Abstract

A CC single-bond-forming reaction from ketones with accompanying CO bond cleavage mediated by a RMgBr or RLi-vanadium (II)-O2 system has been accomplished. Different from conventional reductive coupling reactions of ketones such as the McMurry coupling, the present method forms a CC single (instead of a double) bond and yields a product that contains components derived from the ketone and the alkylating reagent in a one-pot ...

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