Preparation, Characterization, and Theoretical Study of Nanoparticles of Triphenylphosphonium Tetrachloroaluminate (III)[P (C6H5) 3H]+[AlCl4]−

S Ghammamy

Index: Ghammamy, Shahriar Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013 , vol. 43, # 4 p. 390 - 394

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Abstract

Triphenylphosphonium tetrachloroaluminate (III)[P (C6H5) 3 H]+[AlCl4]−, TPPTCA, nanoparticle was synthesized by using triphenylphosphonium chloride addition to AlCl3 in the presence of surfactant. The product was characterized by spectroscopic and analytical methods such as 31P-NMR, FT-IR, XRD, SEM, and CHN. Theoretical calculations were used for the structural optimization of this compound. The structure of compound has been ...