Green Chemistry

Synthesis of 6-substituted phenanthridines by metal-free, visible-light induced aerobic oxidative cyclization of 2-isocyanobiphenyls with hydrazines

…, L Li, G Lin, Q Wang, P Zhang, Z Mao, L Zhou

Index: Xiao, Tiebo; Li, Linyong; Lin, Guoliang; Wang, Qile; Zhang, Ping; Mao, Zong-Wan; Zhou, Lei Green Chemistry, 2014 , vol. 16, # 5 p. 2418 - 2421

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Citation Number: 59

Abstract

A practical synthesis of phenanthridines is of considerable interest in the fields of organic and pharmaceutical chemistry, 1 since this basic skeleton is widespread in naturally occurring alkaloids and exhibits interesting biological activities. 2 Recently, a cascade radical pathway involving C-radical addition to 2-isocyanobiphenyls and subsequently intramolecular homolytic aromatic substitution has been developed, which allows the rapid assembly of a phenanthridine ...

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