Reactions of perfluoroaromatic compounds with ethereal solutions of methylmagnesium iodide in the presence of silver (I) and copper (I) salts
AA Bogachev, LS Kobrina, GG Yakobson
Index: Bogachev, A. A.; Kobrina, L. S.; Yakobson, G. G. Journal of Fluorine Chemistry, 1990 , vol. 48, # 1 p. 85 - 97
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Citation Number: 3
Abstract
Abstract The reactions of hexafluorobenzene, octafluorotoluene, decafluorodiphenyl, and octafluoronaphthalene with ethereal solutions of methylmagnesium iodide in the presence of AgCl or CuI gave the products of the methylation and 1-ethoxy-ethylation of the perfluorinated substrates, whose formation has been suggested to occur with participation of free radicals. Substitution of fluorine atoms by the 1-ethoxyethyl radicals in C6F5CF3 and ...
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