1, 3-Dioxolane formation via Lewis acid-catalyzed reaction of ketones with oxiranes

DS Torok, JJ Figueroa, WJ Scott

Index: Torok, Daniel S.; Figueroa, John J.; Scott, William J. Journal of Organic Chemistry, 1993 , vol. 58, # 25 p. 7274 - 7276

Full Text: HTML

Citation Number: 59

Abstract

1, 3-Dioxolanes are among the most widely used protecting groups for carbonyl compound^.^ The most common methods for the synthesis of these acetals employ protic acids, aqueous conditions, or high temperatures, making them unsuitable for the protection of sensitive compounds. A gentle, low temperature method for the formation of ethylene acetals might involve the acidcatalyzed addition of an epoxide to a ketone. Bogert and ...

Related Articles:

Photochemistry of alkyl halides. 10. Vinyl halides and vinylidene dihalides

[Kropp, Paul J.; McNeely, Steven A.; Davis, Robert Drummond Journal of the American Chemical Society, 1983 , vol. 105, # 23 p. 6907 - 6915]

Photochemistry of alkyl halides. 10. Vinyl halides and vinylidene dihalides

[Kropp, Paul J.; McNeely, Steven A.; Davis, Robert Drummond Journal of the American Chemical Society, 1983 , vol. 105, # 23 p. 6907 - 6915]

Photochemistry of organic halides: Some interesting features of the photobehaviour of vinyl halides and vinylidine dihalides derived from camphene

[Sonawane, H. R.; Nanjundiah, B. S.; Panse, M. D. Tetrahedron Letters, 1985 , vol. 26, # 29 p. 3507 - 3510]

Vinyl azides in heterocyclic synthesis. Part 6. Synthesis of isoquinolines by intramolecular aza-Wittig reaction

[Bauduin, G.; Bondon, D.; Pietrasanta, Y.; Pucci, B. Tetrahedron, 1980 , vol. 36, # 2 p. 245 - 254]

More Articles...