One-pot synthesis of C 8 aldehydes/alcohols from propylene using eco-friendly hydrotalcite supported HRhCO (PPh 3) 3 catalyst

SK Sharma, VK Srivastava, RS Shukla…

Index: Sharma, Sumeet K.; Srivastava, Vivek K.; Shukla, Ram S.; Parikh, Parimal A.; Jasra, Raksh V. New Journal of Chemistry, 2007 , vol. 31, # 2 p. 277 - 286

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Citation Number: 21

Abstract

A multi-functional catalyst [HF/HT] containing a rhodium complex, HRh (CO)(PPh3) 3 [HF] and a solid base, hydrotalcite Mg1− xAlx (OH2) x+ (CO32−) x/n· mH2O [HT], synthesized by impregnation of [HF] onto the surface of [HT], was investigated for the one-pot synthesis of C8 aldol derivatives (aldehydes or alcohols) from propylene. The catalyst was found to be efficient to carry out hydroformylation, aldol condensation and hydrogenation reactions in ...

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