… (R= C6H5, C6H11). Interconversion of cluster-bound phosphine and phosphido ligands. Crystal and molecular structures of [(μ2-H) Os3 (CO) 10 (μ2-P (C6H5) H)] and …

K Natarajan, L Zsolnai, G Huttner

Index: Natarajan, Karuppannan; Zsolnai, Laszlo; Huttner, Gottfried Journal of Organometallic Chemistry, 1981 , vol. 220, # 3 p. 365 - 382

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Citation Number: 50

Abstract

Abstract Monoorganophosphines react with Os 3 (CO) 12 in presence of trimethylamine oxide to give the phosphine-substituted cluster [Os 3 (CO) 11 (PRH 2)] and the phosphido- bridged hydrido cluster [(μ 2-H) Os 3 (CO) 10 (μ 2-PRH)](R= C 6 H 5, p-CH 3 OC 6 H 4, C 6 H 11). The thermolysis of [Os 3 (CO) 11 (PRH) 2)] gave, under different conditions,[(μ 2-H) Os 3 (CO) 10 (μ 2-PRH)] and [(μ 2-H) 2 Os 3 (CO) 9 (μ 3-PR)], and the thermolysis of [(μ 2- ...