Synthesis of [Ag (NH CMe2) 2] ClO4 and Its Use as a Source of Acetimine. 1. Synthesis of the First Acetimine Rhodium Complexes and the First Crystal Structure of a …

…, MT Chicote, R Guerrero, I Vicente-Hernández…

Index: Vicente, Jose; Chicote, Maria-Teresa; Guerrero, Rita; Vicente-Hernandez, Inmaculada; Jones, Peter G. Inorganic Chemistry, 2003 , vol. 42, # 23 p. 7644 - 7651

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Citation Number: 14

Abstract

The mentioned difficulties in the preparation and handling of acetimine account for the scarcity of complexes with this ligand. In fact, acetimine itself has not been used in the various syntheses of metal−acetimino complexes reported so far, 14-29 namely (i) the reaction of acetone with ammine complexes of Cr 0 , Mo 0 , W 0 , Fe II , Mn I , 14 Au I , 15,16 Os II ; 17 (ii) the reactions in acetone between ammonium salts and complexes containing acetylacetonato ligands (Au I ), 16 ...