Solvolysis of diphenyl amidophosphates in aqueous alcoholic media

F Kašpárek, J Mollin

Index: Kasparek, Frantisek; Mollin, Jiri Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 2 p. 386 - 396

Full Text: HTML

Citation Number: 2

Abstract

Abstract Influence of substituent on the reaction rate of the alkali-catalyzed solvolysis of the studied compound set has been followed. The activation entropy has also been determined. The reaction products have been identified, and their concentration ratio has been determined. The reaction selectivity is mostly influenced by sterical effects in the substrate molecule. The results obtained agree with the SN 2 mechanism.

Related Articles:

O-ethyl phosphoramidic acids with sterically demanding N-substituents: useful precursors of ethyl metaphosphate on thermolysis

[Quin, Louis D.; Jankowski, Stefan Journal of Organic Chemistry, 1994 , vol. 59, # 16 p. 4402 - 4409]

O-ethyl phosphoramidic acids with sterically demanding N-substituents: useful precursors of ethyl metaphosphate on thermolysis

[Quin, Louis D.; Jankowski, Stefan Journal of Organic Chemistry, 1994 , vol. 59, # 16 p. 4402 - 4409]

More Articles...