Enantioselective C C Bond Ligation Using Recombinant Escherichia coli??Whole??Cell Biocatalysts

PD de Maria, T Stillger, M Pohl, M Kiesel…

Index: De Maria, Pablo Dominguez; Stillger, Thomas; Pohl, Martina; Kiesel, Michael; Liese, Andreas; Groeger, Harald; Trauthwein, Harald Advanced Synthesis and Catalysis, 2008 , vol. 350, # 1 p. 165 - 173

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Citation Number: 35

Abstract

Abstract Thiamine diphosphate (ThDP)-dependent enzymes like benzaldehyde lyase from Pseudomonas fluorescens (BAL) and benzoylformate decarboxylase from Pseudomonas putida (BFD) are versatile biocatalysts for the C [BOND] C bond ligation of aldehydes to form enantiomerically pure 2-hydroxy ketones. However, the large-scale application of this enzyme class is often restricted by the required external addition of the expensive cofactor ...

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