Une synthèse originale et rapide de (méthyldiéthoxysilyl) benzènes fonctionnels

S Cros, B Bennetau, J Dunoguès, P Babin

Index: Cros, S.; Bennetau, B.; Dunogues, J.; Babin, P. Journal of Organometallic Chemistry, 1994 , vol. 468, # 1-2 p. 69 - 74

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Abstract

Abstract In the presence of a catalytic amount of tetrakis (triphenylphosphine) palladium (0), the 1, 1, 2, 2-tetraethoxydimethyldisilane reacts with various functional bromoarenes giving the corresponding aryldiethoxymethylsilanes in good yields. The creation of Si C Ar bonds involving a polyalcoxydisilane as the silylating reagent is here reported for the first time.

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