Oxidation of Alcohols and vic??Diols with H2O2 by Using Catalytic Amounts of N??Methylpyrrolidin??2??one Hydrotribromide

JK Joseph, SL Jain, B Sain

Index: Joseph, Jomy K.; Jain, Suman L.; Sain, Bir European Journal of Organic Chemistry, 2006 , # 3 p. 590 - 594

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Citation Number: 12

Abstract

Abstract A variety of secondary alcohols, 1, 2-diols and primary alcohols were selectively oxidized in excellent yields to their corresponding ketones, 1, 2-diketones and aldehydes with aqueous 30% hydrogen peroxide in refluxing acetonitrile in the presence of catalytic amounts of N-methylpyrrolidin-2-one hydrotribromide (MPHT).(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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