Cross-coupling reactions of aryl and vinyl chlorides catalyzed by a palladium complex derived from an air-stable H-phosphonate

L Ackermann, CJ Gschrei, A Althammer…

Index: Ackermann, Lutz; Gschrei, Christian J.; Althammer, Andreas; Riederer, Melanie Chemical Communications, 2006 , # 13 p. 1419 - 1421

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Citation Number: 44

Abstract

A palladium complex derived from air-stable TADDOLP(O)H catalyzes efficiently Hiyama, Stille, Kumada and Suzuki cross-coupling reactions of aryl and vinyl chlorides. ... At the outset of our studies, we probed the catalytic activity of palladium complexes derived from different heteroatom-substituted secondary phosphine oxides in Hiyama cross-coupling reactions with aryl chloride 1a (Table 1). In contrast to our studies on Suzuki coupling reactions, 7 ...

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