Synthesis of mutagenic amino-α-carbolines AαC and MeAαC by the thermal electrocyclic reaction of 2-azahexa-1, 3, 5-triene intermediates

日比野俐， 杉野栄一， 田剛志， 小倉直樹…

Index: Chemical and Pharmaceutical Bulletin, , vol. 39, # 1 p. 79 - 80

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Citation Number: 18

Abstract

Page 1. Pharmaceutical Society of Japan ... Pharm. Butt.39(1) 79-80 (]991) ... reaction fo11owedby aza-Wittig reactionS) to givea carbodiimide (2)as a highlyreactive 2-azahexa-1,3,5- trieneintermediate, which readily under- goes electrocyclic ring closure fo11owedby 1,3-hydrogen ...