Geminal dihalides from the oxidation of pivalaldehyde hydrazone by interhalogens

AJ Fry, JN Cawse

Index: Fry,A.J.; Cawse,J.N. Journal of Organic Chemistry, 1967 , vol. 32, p. 1677 - 1679

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Citation Number: 9

Abstract

2, X= Br 3, x= c1 nor 1, 1-dichloroneopentane was found; if they had been present in 1 to 2% yield, they would have been observed easily in our vpc analyses. No rearranged halides were formed; this is to be contrasted with substantial amounts of rearranged products upon oxidation by bromine (30Y0) or chlorine Table I gives the yields of halides formed by the reaction under various conditions. The amount of azine formed was approximately ...