The Journal of Organic Chemistry

Halomethyl-metal compounds. 70. Reaction of phenyl (trihalomethyl) mercury compounds with azodicarboxylate esters. New route to hydrazonodihalomethanes of …

D Seyferth, HM Shih

Index: Seyferth,D.; Shih,H. Journal of Organic Chemistry, 1974 , vol. 39, # 16 p. 2329 - 2335

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Citation Number: 18

Abstract

The reaction of phenyl (trihalomethy1) mercury compounds with azodicarboxylate esters in benzene at SO" gives hydrazonodihalomethanes of type (ROzC) zNN= CX*(X= C1 and/or Br). Sodium trichloroacetate reacts similarly, giving the same type of product (X= Cl). A study of this reaction (R= Me) as carried out at room temperature provided evidence for an intermediate in these reactions to which structure 10 was tentatively as-signed on the ...

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