Interesting reaction of the indanone oximes under Beckmann rearrangement conditions

Y Torisawa, T Nishi, J Minamikawa

Index: Torisawa, Yasuhiro; Nishi, Takao; Minamikawa, Jun-Ichi Bioorganic and Medicinal Chemistry Letters, 2002 , vol. 12, # 3 p. 387 - 390

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Citation Number: 26

Abstract

Attempted Beckmann rearrangement of the 6-methoxyindanone oximes in conventional conditions resulted in the formation of the two kinds of unexpected products: 2- sulfonyloxyindanone and the dimeric product. Related rearrangement was also observed in the reaction with RhCl–trifluoromethansulfonic acid system.

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