Journal of fluorine chemistry

Copper-catalyzed addition of perfluoroalkyl iodides to unsaturated alcohols and transformation of the addition products

M Kotora, M Hácek, B Ameduri, B Boutevin

Index: Kotora, M.; Hajek, M.; Ameduri, B.; Boutevin, B. Journal of Fluorine Chemistry, 1994 , vol. 68, # 1 p. 49 - 56

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Citation Number: 43

Abstract

Abstract Iodoperfluoroalkyl alcohols RF CH 2 CHI (CR 2) n OH (RF= C 6 F 13; R= H, CH 3; n= 1–3, 9) have been readily prepared in high yield by the addition of perfluoroalkyl iodides RFI to allylic and other unsaturated alcohols at 120 C in the presence of a catalytic amount (10% mol) of metallic copper powder. The dibenzoyl peroxide-induced reaction gave lower yields of the addition products in most cases. The chemical changes of ...

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