Synthesis and structure of planar chiral, bifunctional aminoboronic acid ferrocene derivatives

AS Batsanov, D Hérault, JAK Howard…

Index: Batsanov, Andrei S.; Herault, Damien; Howard, Judith A. K.; Patrick, Leonard G. F.; Probert, Michael R.; Whiting, Andrew Organometallics, 2007 , vol. 26, # 9 p. 2414 - 2419

Full Text: HTML

Citation Number: 27

Abstract

N, N'-Diisopropylferrocenecarboxamide is utilized for a directed metalation using n- butyllithium-(-)-sparteine to access planar chiral bifunctional aminoboronate ferrocene derivatives after amide reduction, providing (p R)-2-[(N, N-diisopropylamino) methyl] ferrocenylboronic acid and derivatives with high enantiomeric excess.

Related Articles:

Pd-Catalyzed Synthesis of Aryl and Heteroaryl Triflones from Reactions of Sodium Triflinate with Aryl (Heteroaryl) Triflates

[Werner, Georg; Butenschoen, Holger Organometallics, 2013 , vol. 32, # 20 p. 5798 - 5809]

Synthesis of ferrocenoate esters, amides and other ferrocenoyl derivatives using ferrocenoyl fluoride. A comparison of the reactions of ferrocenoyl fluoride in [bmim][BF …

[Imrie, Christopher; Elago, Elago R.T.; Williams, Nadia; McCleland, Cedric W.; Engelbrecht, Pieter Journal of Organometallic Chemistry, 2005 , vol. 690, # 21-22 p. 4959 - 4966]

Ferrocenecarboxylic acids from substituted ferrocenes. A convenient and versatile oxidation method

[Journal of Organic Chemistry, , vol. 41, p. 3331 - 3332]

Synthesis and structure of novel chiral oxazolinylferrocenes and oxazolinylferrocenylphosphines, and their rhodium (I)-complexes

[Nishibayashi, Yoshiaki; Segawa, Kyohei; Arikawa, Yasuyoshi; Ohe, Kouichi; Hidai, Masanobu; Uemura, Sakae Journal of Organometallic Chemistry, 1997 , vol. 545-546, p. 381 - 398]

Synthesis of ferrocenoate esters, amides and other ferrocenoyl derivatives using ferrocenoyl fluoride. A comparison of the reactions of ferrocenoyl fluoride in [bmim][BF …

[Imrie, Christopher; Elago, Elago R.T.; Williams, Nadia; McCleland, Cedric W.; Engelbrecht, Pieter Journal of Organometallic Chemistry, 2005 , vol. 690, # 21-22 p. 4959 - 4966]

More Articles...