Bis (Tetramethylselenophosphoramidoyl) Methylamine Complexes of Cd (Ii) and Zn (Ii): Synthesis and Multinuclear (31P, 77Se, and 113Cd) Nmr Characterization in …

M Bennis, K Alouani

Index: Bennis, Meriem; Alouani, Khaled Phosphorus, Sulfur and Silicon and the Related Elements, 2012 , vol. 187, # 12 p. 1490 - 1497

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Citation Number: 4

Abstract

Five new complexes ZnL 2 (ClO 4 ) 2 (1), CdL 2 (ClO 4 ) 2 (2), CdL 2 (BF 4 ) 2 (3), CdLCl 2 (4), and CdL(NO 3 ) 2 (5) [L = ((Me 2 N) 2 PSe) 2 NMe] have been synthesized and characterized by elemental analysis, infrared (IR) and multinuclear ( 31 P, 77 Se, and 113 Cd), and nuclear magnetic resonance (NMR) spectroscopy. The 31 P and 77 Se NMR data showed that the title ligand is coordinated in a bidentate fashion to the metal center via its both P=Se groups. ...