The Pinacol—Pinacolone Rearrangement. VI. The Rearrangement of Symmetrical Aromatic Pinacols

WE Bachmann, JW Ferguson

Index: Bachmann; Ferguson Journal of the American Chemical Society, 1934 , vol. 56, p. 2081,2083

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Citation Number: 42

Abstract

In continuation of our studies on the pinacolpinacolone rearrangement, we have prepared ten symmetrical aromatic pinacols of the type RIR~ C-(OH)(HO) CReR1 and have subjected them to rearrangement. We were particularly interested in pinacols containing the p- ethoxyphenyl (phenetyl) and, m-methoxyphenyl groups in order to obtain the migration aptitudes of these groups. Bachmann and &losera found that it is possible to predict ...