Reaction of fluoroalkanols with fluoroalkylamines

V Dědek, F Liška, L Cvak

Index: Dedek,V. et al. Collection of Czechoslovak Chemical Communications, 1978 , vol. 43, p. 985 - 997

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Citation Number: 8

Abstract

2, 2-Dichloro-I, I-difluoroethyl-diethylamine (II) was prepared by addition of diethylamine to I, I-dichlorodifluoroethylene. The reaction of 11 with I-butanol is analogous to that of 2-chloro-- I, I, 2-trifluoroethyl-diethylamine (I), and affords 1-lluorobutane and N, N- dicthyldichloroacetamide (Ill). Reaction of 11 with fluoroalkanol s I V-VI at room temperature gives only amino ethers (eg VI11) which are hydrolysed to dichloroacetates IX-Xl. ...

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