Chemische Berichte

Zur Kenntnis des Imins, III. Phosphin??iminium??chloride und Triphenylphosphin??imin

R Appel, A Hauss

Index: Appel,R.; Hauss,A. Chemische Berichte, 1960 , vol. 93, p. 405 - 411

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Citation Number: 50

Abstract

Abstract Durch Einwirkung von Chloramin auf tertiäre Phosphine werden Phosphin-iminium- chloride,[R 3 PNH 2] Cl, erhalten. Die Deprotonierung des Triphenylphosphin-iminium- chlorids mit Natriumamid in flüssigem Ammoniak liefert Triphenylphosphin-imin; es ist mit dem isosteren Triphenylphosphin-methylen zu vergleichen. Seine Reaktion mit polarisierbaren Sauerstoffverbindungen führt zu einem Austausch des Sauerstoffs gegen ...

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