Conformational studies of EPh 3 M (CO) 5 complexes (E P, As or Sb; M Cr, Mo or W)

MS Davies, GW Allen, MJ Aroney, TW Hambley…

Index: Davies, M. S.; Allen, G. W.; Aroney, M. J.; Hambley, T. W.; Pierens, R. K. Journal of Molecular Structure, 1994 , vol. 326, p. 81 - 92

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Citation Number: 3

Abstract

Abstract Studies are reported of the electro-optical Kerr effect, electric dipole moments and IR carbonyl stretching frequencies of the nine EPh 3 (CO) 5 complexes (E P, As or Sb and M Cr, Mo or W). The experimental results are applied in conjunction with molecular mechanics calculations and data from X-ray crystal structure analysis, to explore the stereostructural preferences of the EPh 3 M (CO) 5 molecules with regard to orientations ...