N-Nitrosoenamines, versatile new synthesis intermediates
R Kupper, CJ Michejda
Index: Kupper, Robert; Michejda, Christopher J. Journal of Organic Chemistry, 1980 , vol. 45, # 14 p. 2919 - 2921
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Citation Number: 12
Abstract
In conclusion, we have shown that DCPH can function as an efficient free-radical trap and thus provide information on the minimum degree of participation of a free-radical mechanism in the reaction of halides with a trimethyltin anionoid. By extension it should be applicable to other nucleophiles whose conjugate acids have pK,'s less than that of DCPH (about 38) and to substrates other than halides.
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