Tetrahedron Letters

Stereospecific synthesis of Z olefins bearing an ω-azido group

A Chhen, M Vaultier, R Carrie

Index: Chhen, A.; Vaultier, M.; Carrie, R. Tetrahedron Letters, 1989 , vol. 30, # 37 p. 4953 - 4956

Full Text: HTML

Citation Number: 12

Abstract

Abstract Ylides derived from ω-azidoalkyltriphenylphosphonium salts were generated at low temperature. They are stable at− 80 C for several hours and react smoothly and stereospecifically with typical aldehydes to form Z-ω-azido olefins which are the precursors of ω-unsaturated primary and secondary amines.

Related Articles:

Synthesis and histamine H2 agonistic activity of arpromidine analogues: replacement of the pheniramine-like moiety by non-heterocyclic groups

[Buschauer, A; Friese-Kimmel A; Baumann, G; Schunack, W European Journal of Medicinal Chemistry, 1992 , vol. 27, # 4 p. 321 - 330]

Synthesis and histamine H2 agonistic activity of arpromidine analogues: replacement of the pheniramine-like moiety by non-heterocyclic groups

[European Journal of Medicinal Chemistry, , vol. 27, # 4 p. 321 - 330]

More Articles...